[1]介孔氮化碳材料合成的研究进展, 物理化学学报, 2016, 32, 1913-1928.
[2]Synthesis of mesoporous carbon nitride via a novel detemplation method and its superior performance in base-catalyzed reactions, Catalysis Science & Technology, 2016, 6, 4192-4200.
[3]Fast and facile preparation of metal-doped g-C3N4 composites for catalytic synthesis of dimethyl carbonate, Applied Catalysis A: General, 2015, 496, 1-8,
硝酸回流,或者氢氧化钠水解试试
低浓度的碱,如NaOH可以和石墨相氮化碳反应。其中,碱与类石墨层边缘的氨基(-NH2和-NH-),使其转化成NH3小分子,结果造成氮化碳层内缩聚程度提高。
当然过渡金属卤化物,如ZnBr2在高温下也可以和氮化碳反应,提高其层内缩聚能力。
而高浓度的碱,如>3M NaOH则很能使石墨相氮化碳发生分解。尤其是介孔氮化碳,和高浓度的无机碱反应时,能明显闻到浓烈的氨气。
见我们课题组的工作:
[1]介孔氮化碳材料合成的研究进展, 物理化学学报, 2016, 32, 1913-1928.
[2]Synthesis of mesoporous carbon nitride via a novel detemplation method and its superior performance in base-catalyzed reactions, Catalysis Science & Technology, 2016, 6, 4192-4200.
[3]Fast and facile preparation of metal-doped g-C3N4 composites for catalytic synthesis of dimethyl carbonate, Applied Catalysis A: General, 2015, 496, 1-8,